To remove an index, use the db.collection.dropIndex() method.
db.users.dropIndex( { "userid": 1 } ) //removes index from userid field
db.users.dropindexes() //removes all indexes from users collection except _id index
To modify the index, you must drop the index first and then recreate the index.
db.users.dropIndex( { "userid": 1 } ) //removes index from userid field
db.users.createIndex( { "userid": 1 }, { unique: true } ) //Unique Index on a Single Field